Software development for simulation of reformer furnace. The thesis studies the simulation, optimization and control structure design using stepwise approach of skogestad. Not only working temperature but also high corrosive mediums are design parameters to be considered. The initial compression has been found to provide product hydrogen at a pressure that can easily reach the desired hydroprocessing pressure with a four or. Chapter 1 introduction this thesis presents a master of science degree project conducted at the department of chemical engineering, at ntnu. Because hydrogen needs within various sectors of the cpi are at their highest levels in history, and are continuing to grow, an understanding of this method of hydrogen production and purification can be useful. Steps of designging a steam methane reformer for syngas production. Hightemperature gascooledreactor steammethane reformer design. Effect of a prereformer on primary reformer performance contd good performance depends on good design and preparation of the reactor it is not simply another catalyst bed guaranteed operation assumes plug flow through the bed guaranteed. The figure also illustrates the position of the foam within the reformer and positions of the n.
The reformer model is validated using experimental results from a small scale model reactor. Hightemperature gascooledreactor steammethane reformer. Aug 30, 2012 in this research, industrial secondary reformer reactor has been modeled and simulated. It is important to ensure that the equipment specified will be capable of achieving the desired yields and selectivity. Disclosed is a new integrated flameless distributed combustionmembrane steam reforming fdcmsr reactor apparatus for steam reforming of any vaporizable hydrocarbon to produce h 2 and co 2, with minimal co, and virtually no co in the h 2 stream. Multiple reactors up to six can be configured with easytouse wizards. Snyder developed a kinetic model of a methane reformer with steam as a design tool. Rti was approached by a client in the gulf states to effectively remove lel from their reformer reactor system in preparation for the removal and reclamation of the. Modeling and design of a multitubular packedbed reactor.
An ebook reader can be a software application for use on a computer such as microsofts free reader application, or a booksized computer this is used solely as a reading device such as nuvomedias rocket ebook. Additionally, heat management, flow distribution and structural integrity are also major concerns affecting reactor performance. If anyone is working with modelling of steam methane reforming with. The haldor topsoe series reactor has been in operation for over 20 years and is a proven way to boost the capacity of plants by up to 80%. The furnace of this reformer contains seven rows of 48 reforming tubes whose external diameter, internal diameter and exposed length are 14. Learn how to create refinery reactor templates fluidized catalytic cracking fcc reactor, hydrocracker reactor and catalytic reformer. Chemical engineering software model chemical units and. Computational fluid dynamics modeling of steam methane reforming reactor. Size reactors either alone or in series once given the molar flow rate of a, and the rate of reaction, r a, as a function of conversion, x. Reformer reactor system cleaning refined technologies inc. Evaluating the performance of a steam reformer with comsol. Gas flex a process gas compressor program utilizing bwr equations of state. Membrane reactor modeling the entire process for h 2production onboard, the membrane reactor was modeled in aspenplus v.
To accurately analyze the performance of a steam reformer design, you need to be able to couple mass, energy, and flow equations. Users can purchase an ebook on diskette or cd, but the most popular method of getting an ebook is to purchase a downloadable file of. May 01, 2010 the reformer furnace design alternatives will be discussed below. Write the mole balances in terms of conversion for a batch reactor, cstr, pfr, and pbr. Conversion and reactor sizing define conversion and space time. Once the kinetics is known, the reactor design can be made based on material balance. A plate reactor where chemical reactions occur throughout and reacting chemicals are introduced at two points in the reactor. Steps of designging a steam methane reformer for syngas. Unisim refining reactors are available within the unisim eo environment, which is an integral part of the unisim evolution, highperformance, next generation platform. The reforming tube investigated in this work belongs to an industrialscale topfired, cocurrent reformer designed by selas fluid processing corporation fig. Simulations with a reformer bed geometry of counter current, multiple tubes performed using the developed model show that heattransfer is limiting the reformer size, requiring 1. Dehydrogenation, an important component of reforming, is a strongly endothermic reaction, and as such, requires the reactor vessel to be externally heated. The reactor is investigated with chemical, thermal, fluidic and mechanical aspects.
Feed gas usually a mixture of hydrogen, methane and other light hydrocarbons is first compressed to about 300 psig. Principles of prereforming technology linkedin slideshare. Developed in the late 50s, atrs main application was for ammonia and methanol syntheses. Rough parameter values can be obtained from handbook and design data. The use of feedback control improves closedloop dynamics and feed disturbance rejection. Control structure design for methanol process ntnu. Reactor design is a vital step in the overall design of a process. However, the software does not have a specific block.
Describes how to use an interactive simulation that solves the differential equations for an autothermal reactor, which is a catalytic reactor in which the feed gas is preheated in an annular. Ansys engineering simulation for reactor design including cfd for chemical reactor design, structural and thermal analysis and instrumentation and control software used for design and analysis of chemical reactors enable reaction engineers to answer whatif questions as they design and enhance reactors performance, energy usage, reactor yield. Understand how to calibrate a catalytic reformer model based on measured data. Autothermal reforming of natural gas to synthesis gas. Design and evaluation of delayed cokers and visbreakers is a thi specialty. May 22, 2005 at the same time, it produces hydrogen h and liquified petroleum gas lpg as its byproducts. The challenges in designing a reactorreformer relate to the minimization of catalyst load, volume catalyst bed to volume of the reactor ratio, and catalyst load to weight of the reactor ratio. Simulate a catalytic reformer and run either standalone or within a hysys petroleum refining flowsheet. May 31, 2010 the reactor is investigated with chemical, thermal, fluidic and mechanical aspects. I am assigned to design a water gas shift reactor to shift the h2. Hello, ive been asked to design a primary reformer for the extraction of hydrogen from methane for haber bosch process final year project. The user can design new processes, troubleshoot existing processes, evaluate alternate plant configurations, or optimize plant yield and efficiency to list a. Aspen hysys reformer is a rigorous reactor model that simulates a naphtha reformer producing reformate for gasoline blends in refineries.
Modeling and simulation of an industrial secondary reformer. This study aims to analyze the feasibility of heat application design of rde reactor in the steam methane reforming for hydrogen production using the chemcad software. This one is unique because it utilized hot nitrogen as the carrier for the high solvency qtrx2 cleaning chemistry the challenge. The reformer for msr in this study is a multitubular packedbed reformer. Reactor calculation using simulation software revised from senior project report by ryan p. Mathematical modeling of an industrial naphtha reformer. The aim is to increase durability of the product by preventing fracture occurred in the reactor because of high temperatures and critical temperature profiles. The reactor shell is usually surrounded by thermal insulation materials to avoid any significant amount of heat loss.
The series reactor configuration means that a significant boost to production can be obtained while maintaining the same gas flow through the plant. Integrated flameless distributed combustionmembrane steam. The outlet temperature of cogeneration heat exchanger is analyzed to be applied as a feed of steam reformer. A reactor comprising only the reformer unit of the designed reformerafterburner combination was built solely for this test. Modeling and design of a multitubular packedbed reactor for. You could choose a tubular reactor or plug flow reactor. In order to create a reactor design model for the secondary reformer in the ammonia plant.
Engineers aide sinet fluid flow analysis, equipment sizing and. Inlet conditions of each reactor were set to outlet conditions of prior reactor in except of temperature that is changed because of intermediate heaters. Autothermal reactor interactive simulation youtube. The structure of the heatexchanger type reformer, including baffles, tubes and a shell, is presented in figure 1. Feb 25, 2015 describes how to use an interactive simulation that solves the differential equations for an autothermal reactor, which is a catalytic reactor in which the feed gas is preheated in an annular. The design or simulation of the catalytic reforming reactor is very difficult because of complicated components of catalytic reforming feedstock, higher operating temperature of the system, and the complicated reactions in the reactor. The sensitivity of catalytic reforming to contamination by sulfur and nitrogen requires hydrotreating the naphtha before it enters the reformer, adding to the cost and complexity of the process. In a batch reactor, the reagents are added together and allowed to react for a given amount of time. Co ratio to be 2, and i have researched that in order to produce methanol, only one single adiabatic high temperature water gas. New engineering graduatestechnologists who will be using aspen hysys in their daily work.
A study on naphtha catalytic reforming reactor simulation and. It contains the tools for you to simulate material transport and heat transfer. Additionally, heat management, flow distribution and structural integrity. This multiplelump reaction system can be used like any other aspen hysys unit operation. Process engineers doing refinery process design and optimization projects and studies. The input to the model were feed flow rate and composition of all lumps in the p 6 p 6 t 1 reactor 1 reactor 2 reactor 3 stabilizer. Figure 05 design the reaction set4 of second reformer. The types of reactors that can be modeled include batch reactors, continuous stirred tank reactors, plug flow reactors, plug flow reactors with axial dispersion, and tubular flow reactors with radial dispersion. Integration of computational fluid dynamics modeling and boundary feedback control. At the same time, it produces hydrogen h and liquified petroleum gas lpg as its byproducts.
Comparison of catalyst geometries for methane steam reforming. Refined technologies has completed an evergrowing number of reactor loop cleaning projects. I use hysys in the chemical process design capstone course, ceng416. How do i calculate the volume of fixed bed reactor using space velocity. Reactors jordan university of science and technology. For an ideal cstr reactor, the residence time required for the reaction is given by. Catalyst design influences process variables such as pressure drop. I am required to design a steam reformer alongside a furnace for a design project. However, the software does not have a specific block to simulate membrane reactors, in which both. High yields of hydrogen production from methanol steam. The process is sootfree due to burner design and fixedbed catalyst. Mathematical modeling of an industrial naphtha reformer with. The developed model can be used for the performance optimization of the whole ice reformer system including design of the reactor.
Using the comsol multiphysics software, you can set up a model of a steam reformer that represents its realworld behavior and operating conditions. Hydrogen production by steam reforming chemical engineering. Fig 1 illustrates the geometry of the presented reactors. Software development for simulation of reformer furnace ijcce. Uop equipment specialists oversee the design, fabrication, and installation providing a singlesource responsibility for this critical hydroprocessing technology feature. Autothermal reforming atr is a lowinvestment process using a simple reactor design. Chemical engineering software model chemical units and reactors. Given the intrinsic kinetics, the tortuosity factor of a nimgal 2 o 4 catalyst was determined under reaction conditions by minimizing the sum of squares of residuals of the exper. Optimizing chemical reactors, filtration equipment, mixers, and other processes is made easy with the chemical reaction engineering module. Page 1 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. Modeling and simulation of an industrial secondary. Rti was approached by a client in the gulf states to effectively remove lel from their reformer reactor system in preparation for the removal and reclamation of the preciousmetal catalyst. Cfd modeling and control of a steam methane reforming reactor.
Paper open access analysis on operating parameter design to. Figure 06 design the reaction set5 of methanator 1 reactor figure 07 design the reaction set6 of ammonia converter reactor 2. The first objective of the thesis is to study the effect of operation conditions such as feed compositions,pressure and temperature on the mole fraction of the product components, temperature and pressure of the. For the adaiabatic reactor, delete the temperature specification and specify the heat duty as 0. Reactor design and catalysts testing for hydrogen production. In the reformer considered the reforming process is carried out in a compact tubular reactor with a centerline thermocouple tube using a 2% ptzrce based catalyst. Sep 24, 20 steam reforming types of reformer design 1.
For an isothermal reactor specify the outlet temperature. The software has so many unit operations and chemical reactor to choose from. Build a new catalytic reformer reactor template and calibrate it using provided data. Application of tracking simulator to steam reforming process. Natural gas reforming process by refomer furnace is commonly used for. Fig 1a shows a tubular reactor with rectangular crosssection. Chemcad safety net plant safety and piping networks software. Model calibration and comparison with industrial plant data.
The challenges in designing a reactor reformer relate to the minimization of catalyst load, volume catalyst bed to volume of the reactor ratio, and catalyst load to weight of the reactor ratio. In a batch reactor, the reagents are added together and. Thi has developed a proprietary computer program for wicketstyle coil sections and can accurately model the heat transfer in these special hightemperature, lowpressure reformer reactor feed and interheaters. Thibault 200102 the proii process simulation program performs rigorous mass and energy balances for a range of chemical processes from oilgas separation to reactive distillation. Preliminary equipment design for onboard hydrogen production. I just want to know how i would use this information to design the reformer. The chemical reactor design tool crdt is a set of computer programs that solves the equations describing common chemical reactor models. Aug 01, 20 effect of a pre reformer on primary reformer performance contd good performance depends on good design and preparation of the reactor it is not simply another catalyst bed guaranteed operation assumes plug flow through the bed guaranteed operation relies on good catalyst management 33. Uops hydroprocessing reactor internals are custom designed and fabricated for each application to ensure maximum performance over the desired range of operating conditions. Recycle gas to reactor feed and combined with cool reformate, to the air cooler, then and recontacting drum then on to recycle gas, treat gas, hydrocracker gas, and gas to the hydrogen plant. The reformer low pressure separator and the reformer separator drum from the separator drums, hydrogen is compressed and can flow to where. This platform allows for design and optimization under the same environment. Reactor models are open and customizable by the user, and are fully integrated with the aspen hysys process model. All major operational reformer variables are available such as feed rate, feed composition, reactor temperatures, recycle rates, and system pressure.
Gambit was the software used to create the geometry and mesh, which was then. In this research, industrial secondary reformer reactor has been modeled and simulated. A study on naphtha catalytic reforming reactor simulation. However, the models especially of reactors like reformers, are not very reliable. The flameless distributed combustion drives the steam reforming reaction which provides great improvements in heat exchange.
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